Tetrahedron p. 4223 - 4234 (1986)
Update date:2022-07-29
Topics: Synthesis Experimental
Baldwin, Jack E.
Adlington, Robert M.
Bottaro, Jeffrey C.
Kolhe, Jayant N.
Perry, Matthew W. D.
Jain, Ashok U.
The lithium salts of aldehyde t-butylhydrazones react with electrophiles (aldehydes, ketones, alkyl halides, crotonates) to form C-trapped t-butylazo-compounds; tautomerisation and hydrolysis gave α-hydroxy ketones, ketones, and γ-keto esters in good yield, thereby providing a convenient new acyl-anion equivalent.Reaction of these lithium salts with aldehydes and ketones, followed by elimination provided a new route to azo alkenes.
View MoreImprove Medical Technology(Nanxiong) Co., Ltd
Contact:86-751-3836997
Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd
Contact:+86-771-2311266
Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Shenzhen HwaGen Pharmaceutical Co., Ltd
website:http://www.rafflespt.com
Contact:+86-752-5538396
Address:Guangdong Huizhou China
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Shanghai united Scientific Co.,Ltd.
Contact:+86-21-53535353
Address:28F No.900 huaihai Road Shanghai China
Doi:10.1016/S0040-4039(00)85971-7
(1983)Doi:10.1016/j.ica.2006.02.023
(2006)Doi:10.1007/s11178-005-0348-y
(2005)Doi:10.1134/S1070428016030210
(2016)Doi:10.1016/j.tet.2005.11.086
(2006)Doi:10.1021/ja034606+
(2003)
