Tetrahedron p. 4223 - 4234 (1986)
Update date:2022-07-29
Topics: Synthesis Experimental
Baldwin, Jack E.
Adlington, Robert M.
Bottaro, Jeffrey C.
Kolhe, Jayant N.
Perry, Matthew W. D.
Jain, Ashok U.
The lithium salts of aldehyde t-butylhydrazones react with electrophiles (aldehydes, ketones, alkyl halides, crotonates) to form C-trapped t-butylazo-compounds; tautomerisation and hydrolysis gave α-hydroxy ketones, ketones, and γ-keto esters in good yield, thereby providing a convenient new acyl-anion equivalent.Reaction of these lithium salts with aldehydes and ketones, followed by elimination provided a new route to azo alkenes.
View MoreJinan Jiaquan Chemical Co.,Ltd
Contact:+86-531-62318366
Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Tianjin Realet Chemical Technology Co.,Ltd.
website:http://www.realetchem.com
Contact:+86-022-58788819
Address:shuanggang industrial park
Guangzhou Flower's Song Fine Chemical CO,. Ltd
Contact:+86-20-87475199
Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Nantong Auxin Electronic Technology Co., LTD
Contact:86-513-88760026
Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
xi'an taima biological engineering co., ltd.
Contact:+8615619038117
Address:6 No,keji road xi'an city of china
Doi:10.1016/S0040-4039(00)85971-7
(1983)Doi:10.1016/j.ica.2006.02.023
(2006)Doi:10.1007/s11178-005-0348-y
(2005)Doi:10.1134/S1070428016030210
(2016)Doi:10.1016/j.tet.2005.11.086
(2006)Doi:10.1021/ja034606+
(2003)
