Journal of Organic Chemistry p. 1182 - 1185 (1984)
Update date:2022-08-05
Topics:
Majerski, Zdenko
Hamersak, Zdenko
4,5-exo-Epoxybrendane (3) rearranged readily with sulfuric acid in acetone, and with boron trifluoride etherate in acetic acid, yielding, upon a hydrolytic workup, 86percent of 2-exo-8-exo-noradamantanediol and 93percent of 8-exo-acetoxy-2-exo-noradamantanol, respectively.Starting epoxide 3 was prepared in 60percent overall yield from readily available 4-brendanone.Consequently, the acid solvolysis of 3 provides a convenient, general entry to the noradamantane system functionalized at carbons 2 and 8.
View MoreJining tiansheng chemical co.,ltd.
Contact:+86-537-5158722
Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Contact:
Address:
Hangzhou Share Chemical Co., Ltd(expird)
Contact:+86-57187093700
Address:Hang Xing Road
ZHUHAI HAIRUIDE BIOSCIENCE AND TECHNOLOGY CO.,LTD
website:http://www.zhhairuide.com
Contact:+8613326687259/+86-756-7789199
Address:No.10 Yonghui Road
Dongying J&M Chemical Co., Ltd,
Contact:546-8551108
Address:Room 1219, Zisheng Mansion, Zibo Road, Dongying, Shandong, China
Doi:10.1016/j.bmcl.2006.02.001
(2006)Doi:10.1246/bcsj.56.3099
(1983)Doi:10.1021/ja00345a047
(1983)Doi:10.1002/ejoc.201200311
(2012)Doi:10.1021/ol060347s
(2006)Doi:10.1016/j.bmcl.2006.02.042
(2006)
