OPTICALLY ACTIVE DIALLYLBIS(2-PHENYLBUTYL)TIN. SYNTHESIS AND APPLICATION TO ASYMMETRIC SYNTHESIS OF HOMOALLYL ALCOHOLS

DOI: 10.1246/cl.1983.1529

Source and publish data:

Chemistry Letters p. 1529 - 1532 (1983)

Update date:2022-08-03

Topics:

Authors:

Otera, Junzo

Kawasaki, Yuzuru

Mizuno, Hirofumi

Shimizu, Yasumi

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Article abstract of DOI:10.1246/cl.1983.1529

Optically active diallylbis(2-phenylbutyl)tin (1) was successfully obtained by the Grignard method.Enantioselective reaction of 1 with various aldehydes afforded homoallyl alcohols in 20 - 80percent optical yields, which are not affected by solvent effect

Full text of DOI:10.1246/cl.1983.1529

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