SYNTHESIS OF MOLYBDENUM-RHODIUM BIMETALLIC COMPLEXES USING, AS LIGANDS, ELECTRON-RICH MOLYBDENUM(0) COMPLEXES CONTAINING AN η6-METHYLDIPHENYLPHOSPHINE LIGAND

Article abstract of DOI:10.1016/0022-328X(83)87024-7

The readily prepared complexes Mo(η⁶-PhPMePh)(PMePh2)2L, (I), (L=P(OMe)3 and CNBu-t) and Mo(η⁶-PhPMePh)(PPh2CH2CH2PPh2)L, (II), (L=PMePh2 and CO) react like tertiary phosphine ligands with 2 to give the binuclear complex