Synthesis, Reactions, and Crystal Structures of Cyclo-η5--(η-arene)-molybdenum and -tungsten Compounds

DOI: 10.1039/c39830000538

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 538 - 540 (1983)

Update date:2022-08-04

Topics:

Authors:

Green, Malcolm L. H.

Izquierdo, Alejandro

Martin-Polo, Jesus J.

Mtetwa, Victor S. B.

Prout, Keith

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Article abstract of DOI:10.1039/c39830000538

The arene rings of W(η-C6H5Me)2 and Mo(η-C6H6)2 are readily displaced by the fulvenes C5H4=CR2 (R=Me or Ph) giving M(η⁵:η¹-C5H4-μ-CR2)(η-arene), M=Mo or W; when M=Mo and R=Me then treatment with HCl gives the binuclear iC5H4)(μ-Cl2)>2 whose crystal structure has been determined and which is a convenient precursor to mono-cyclopentadienylmolybdenum derivatives.

Full text of DOI:10.1039/c39830000538

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