ASYMMETRIC PINACOL-TYPE REARRANGEMENT OF α-HYDROXY METHANESULFONATES PROMOTED BY TRIETHYLALUMINIUM - PREPARATION OF OPTICALLY PURE α-ARYL AND α-VINIL KETONES -

DOI: 10.1016/S0040-4039(01)99831-4

Source and publish data:

Tetrahedron Letters p. 4997 - 5000 (1983)

Update date:2022-08-04

Topics:

Authors:

Suzuki, Keisuke

Katajama, Eiji

Tsuchihashi, Gen-ichi

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Article abstract of DOI:10.1016/S0040-4039(01)99831-4

Asymmetric (stereospecific) pinacol-type rearrangement of aryl or vinyl group in α-hydroxy methansulfonates is promoted by Et3Al in CH2Cl2 at -78 grad C to afford optically pure α-aryl or α-vinyl ketones

Full text of DOI:10.1016/S0040-4039(01)99831-4

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