Carbohydrate Research p. 193 - 202 (1980)
Update date:2022-08-04
Topics:
Ito, Hiroshi
Eby, Ronald
Kramer, Steven
Schuerch, Conrad
1,3-Anhydro-2,4,6-tri-O-benzyl-β-D-glucopyranose has been synthesized by ring closure of 2,4,6-tri-O-benzyl-α-D-glucopyranosyl chloride via two reaction sequences.The preferable method has allyl 3-O-allyl D-glucopyranoside as key intermediate.This appears to be the first example of an anhydro sugar derivative with the 2,6-dioxabicyclo<3.1.1>heptane skeleton.
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