Organometallic Complexes as Ligands. Synthesis of trans- (R=p-OMeC6H4, CH3, c-C6H11, t-Bu) and New Information on the Isocyanide Insertion into the Pd-C ? bond

Article abstract of DOI:10.1007/BF00799028

The pyridyl complex trans-2>(PPh3)2> easily undergoes insertion of isocyanides into the palladium-carbon bond via an ionic intermediate to give the title compounds.Details on the insertion pathway were obtained through IR, 31