Advanced Synthesis and Catalysis p. 5239 - 5244 (2019)
Update date:2022-08-03
Topics:
Qiu, Di
Lian, Chang
Mao, Jinshan
Ding, Yi
Liu, Zerong
Wei, Liyan
Fagnoni, Maurizio
Protti, Stefano
A visible light-induced formation of Aryl-Phosphorous bonds starting from arylazo sulfones and triaryl (or trialkyl)phosphites in the absence of any photoredox catalyst and any additives was developed. This reaction showed a broad substrate scope and afforded (hetero)aryl phosphonates in good yields and in up to the gram scale.
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