The conformational bias of aryl, arylsulfonyl geminally substituted tertiary carbon centers: Applications in substrate-based stereocontrol

DOI: 10.1039/b601647b

Source and publish data:

Organic and Biomolecular Chemistry p. 1806 - 1810 (2006)

Update date:2022-08-02

Topics:

Authors:

Scott, Jeremy P.

Mullens, Peter R.

Brewer, Sarah E.

Brands, Karel M.J.

Chilenski, Jennifer R.

Davies, Antony J.

Gibb, Andrew D.

Lieberman, David R.

Oliver, Steven F.

Dolling, Ulf-H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/b601647b

Intramolecular nitrile oxide-olefin cycloaddition to form hexahydrobenzisoxazole 14, which engenders a phenylsulfonyl, 2,5-difluorophenyl geminally substituted carbon substructure, proceeds with up to 99% ds. A rationalization of the high level of substra

Full text of DOI:10.1039/b601647b

Products guided by the article

Product name:2-[3-phenyl-3-(2,5-difluorophenylsulfonyl)hex-5-en-1-yl]-1,3-dioxolane

Cas No:893413-02-0

R&D Labs maybe for 893413-02-0

ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Jiangsu Institute of Ecomones Co., Ltd

website:http://www.jsmone.com

Contact:+86-519-82821700

Address:95 Huanyuan N. Road, Jintan, Jiangsu, China
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Beyond Pharmaceutical Co., Ltd

Contact:+86-571-8195-3185

Address:No. 13-1, Liansheng Road, Yuhang District

Relevant to this article

CROSS-CONJUGATED BIRADICALS. KINETICS AND KINETIC ISOTOPE EFFECTS IN THE THERMAL ISOMERIZATIONS OF CIS- AND TRANS-2,3-DIMETHYLMETHYLENECYCLOPROPANE, CIS- AND TRANS-3,4-DIMETHYL-1,2-DIMETHYLENECYCLOBUTANE, AND OF 1,2,8,9-DECATETRAENE

Doi:10.1016/0040-4020(82)80166-X
(1982)
Doi:10.1039/jr9500001722
(1950)
SELECTIVE HYDROESTERIFICATION OF ALKYNES TO MONO- OR DIESTERS

Doi:10.1016/S0040-4039(00)94174-1
(1983)
CONVERSION OF KETONES TO TRISUBSTITUTED OLEFINS UNDER NEUTRAL CONDITIONS

Doi:10.1016/S0040-4039(00)99859-9
(1984)
Selective oxymetalation of terminal alkynes via 6-endo cyclization: mechanistic investigation and application to the efficient synthesis of 4-substituted isocoumarins

Doi:10.1039/c8sc01537f
(2018)
MIGRATORY-INSERTION REACTIONS INVOLVING THE THIOCARBONYL LIGAND. dihapto-THIOACYL COMPLEXES FROM THE REARRANGEMENT OF ARYLTHIOCARBONYL COMPLEXES OF OSMIUM (II). STRUCTURE OF Os(η²-CSR)(η¹-O2CCF3)(CO)(PPh3)2

Doi:10.1016/0022-328X(83)87165-4
(1983)

Article Doi