Chemistry of Heterocyclic Compounds p. 1197 - 1201 (1983)
Update date:2022-08-04
Topics:
Grishina, G. V.
Potapov, V. M.
Abdulganeeva, S. A.
Ivanova, I. A.
It has been shown that the addition of methyl acrylate and acrylonitrile to the pyrrolidine enamines of 1-methyl-, (1S)-α-phenylethyl-, (1S)-sec-butyl, 1,2-dimethyl, and 1,3-dimethyl-4-piperidone results in the formation of 3- or 5-substituted 4-piperidones, depending on the reaction conditions and the structure of the enamine.The formation of a pair of diastereomers of the 3-substituted 4-piperidones in a 1:1 ratio takes place when there is a chiral substituent on the nitrogen atom in the piperidone ring.
View MoreContact:+1-284-4950244
Address:Box 3069, Road Town, Tortola, British Virgin Islands
Shanghai birch chemical technology co.,ltd
Contact:+86-21-54096810
Address:No.2588,Jungong Road,Shanghai,China
website:http://www.simagchem.com
Contact:+86-592-2680277
Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Contact:+86-871-65217109
Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences
Contact:+86-575-82733999 0575-82732999
Address:hangzhou gulf fine chemical zone,shangyu city,zhejiang province
Doi:10.1016/0008-6215(84)85377-X
(1984)Doi:10.1002/hlca.19640470605
(1964)Doi:10.1007/BF00842825
(1983)Doi:10.1039/c5tb01938a
(2015)Doi:10.3762/bjoc.14.172
(2018)Doi:10.1016/0022-328X(84)80118-7
(1984)
