Tetrahedron Letters p. 15 - 18 (1984)
Update date:2022-08-02
Topics:
Fankhauser, John E.
Peevey, Richard M.
Hopkins, Paul B.
Anhydrous chloramine T in methanol is a highly effective reagent for the conversion of allylic phenyl selenides to the corresponding rearranged N-allylic-p-toluenesulfonamides.The reaction presumably proceeds via an allylic selenimide intermediate which undergoes <2,3>-sigmatropic rearrangement.
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(1940)
