Novel Rearrangement of 1,4-Ylidic Thiaanthracenes

DOI: 10.1021/jo00187a033

Source and publish data:

Journal of Organic Chemistry p. 2472 - 2478 (1984)

Update date:2022-08-03

Topics:

Authors:

Ohno, Sachio

Shimizu, Hiroshi

Kataoka, Tadashi

Hori, Mikio

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Article abstract of DOI:10.1021/jo00187a033

A novel rearrangement of 10-alkyl-9-aryl-10-thiaanthracenes is described. 9-Mesityl-10-methyl-10-thiaanthracene (8a) generated by proton abstraction of 9-mesityl-10-methylthioxanthenium perchlorate (7a) with sodium hydride in THF underwent thermal rearran

Full text of DOI:10.1021/jo00187a033

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