ASYMMETRIC ACYLATION OF CARBOXAMIDES HAVING trans-2,5-BIS(METHOXYMETHOXYMETHYL)PYRROLIDINE MOIETY AS A CHIRAL AUXILIARY AND STEREOSELECTIVE REDUCTION OF THE RESULTING 2-ALKYL-3-OXO AMIDES

DOI: 10.1016/S0040-4039(01)81747-0

Source and publish data:

Tetrahedron Letters p. 6015 - 6016 (1984)

Update date:2022-07-30

Topics:

Authors:

Ito, Yoshio

Katsuki, Tsutomu

Yamaguchi, Masaru

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81747-0

trans-2,5-Bis(methoxymethoxymethyl)pyrrolidine proved to be an excellent chiral auxiliary for the asymmetric acylation of the corresponding carboxamide enolates and the stereoselective Zn(BH4)2 reduction of the resulting 2-alkyl-3-oxo amides provided a us

Full text of DOI:10.1016/S0040-4039(01)81747-0

Products guided by the article

Product name:(2S,5S,2'S)-N-(2'-methyl-3'-oxo-3'-phenylpropionyl)-2,5-bis(methoxymethoxymethyl)pyrrolidine

Cas No:90290-42-9

R&D Labs maybe for 90290-42-9

Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Jilin Tiandicheng Biotech Co.,Ltd

Contact:+86-18103315327

Address:jinlin
Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
Shanghai Jinsheng Pharmaceutical Co., Ltd.

website:https://www.jspharmatech.com/

Contact:021-33933512 13651960330

Address:Shanghai
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China

Relevant to this article

Doi:10.1021/jo00832a060
(1970)
Doi:10.1021/jo01042a018
(1963)
THE EFFECT OF THE α-CYANO MOIETY ON NEIGHBORING GROUP PARTICIPATION BY THE CYCLOPROPYL GROUP

Doi:10.1016/S0040-4039(01)92473-6
(1981)
A novel class of potent 3-isoxazolol GABA_A antagonists: Design, systhesis, and pharmacology [3]

Doi:10.1021/jm000371q
(2000)
Doi:10.1007/BF00479572
()
Hyperbranched architectures for NLO polymers

Doi:10.1080/10587250108023698
(2001)

Article Doi