Helvetica Chimica Acta p. 1467 - 1469 (1982)
Update date:2022-07-30
Topics:
Jefford, Charles W.
Bernardinelli, Gerald
Rossier, Jean-Claude
Zuber, Jacques A.
A new product arising from the reaction of dichlorocarbene with norbornadiene, 6endo-(2,2-dichlorovinyl)-cis-bicyclo<3.1.0>hex-2-ene, is described.It does not arise from the normal exo-1,2-adduct, but possibly originates by sigmatropic rearrangement of an initially formed zwitterionic intermediate.
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