
Journal of the Chemical Society. Chemical communications p. 214 - 215 (1984)
Update date:2022-08-02
Topics:
Sugahara, Tsutomu
Komatsu, Yuuki
Takano, Seiichi
(+)-Polyzonimine (1), a terpenoid insect repellent produced by a millipede, was synthesized by a reaction sequence which utilizes the asymmetric <2,3> sigmatropic rearrangement of the ammonium ylide formed from the salt (10) to generate the chiral interme
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