A New Method of Formation of 9-Azabicyclononane Skeleton and Its Application to Synthesis of (+/-)-Anatoxin a

DOI: 10.1246/cl.1987.919

Source and publish data:

Chemistry Letters p. 919 - 922 (1987)

Update date:2022-08-04

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Authors:

Shono, Tatsuya

Matsumura, Yoshihiro

Uchida, Kenshi

Tagami, Katsumi

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Article abstract of DOI:10.1246/cl.1987.919

9-Azabicyclo<4.2.1>-nonane skeleton was formed in one step by Lewis acid promoted reaction between 1-methoxycarbonyl-2,5-dimethoxypyrrolidine and 1-ethoxy-1-trimethylsiloxy-1,4-pentadiene, and it was converted to (+/-)-anatoxin a.

Full text of DOI:10.1246/cl.1987.919

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