PUMMERER REARRANGEMENTS USING CHLOROTRIMETHYLSILANE

DOI: 10.1016/S0040-4039(01)80094-0

Source and publish data:

Tetrahedron Letters p. 1039 - 1042 (1984)

Update date:2022-09-26

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Authors:

Lane, Simon

Quick, Stephen J.

Taylor, Richard J. K.

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Article abstract of DOI:10.1016/S0040-4039(01)80094-0

Pummerer rearrangements of 3-carbomethoxythian-4-one S-oxide (1) have been investigated and chlorotrimethylsilane found to be the reagent of choice for preparing the corresponding α,β-unsaturated sulphides (2 and 3).Related chlorotrimethylsilane-induced Pummerer rearrangements are also reported.

Full text of DOI:10.1016/S0040-4039(01)80094-0

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