Tetrahedron Letters p. 1039 - 1042 (1984)
Update date:2022-09-26
Topics:
Lane, Simon
Quick, Stephen J.
Taylor, Richard J. K.
Pummerer rearrangements of 3-carbomethoxythian-4-one S-oxide (1) have been investigated and chlorotrimethylsilane found to be the reagent of choice for preparing the corresponding α,β-unsaturated sulphides (2 and 3).Related chlorotrimethylsilane-induced Pummerer rearrangements are also reported.
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