Ionic Bicyclobutane as an Intermediate in the Reaction of PhS- with 3-Halobicyclobutanecarbonitrile: Comparison between Thio- and Oxycarbenium Ions

DOI: 10.1021/jo00192a008

Source and publish data:

Journal of Organic Chemistry p. 3285 - 3291 (1984)

Update date:2022-08-03

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Authors:

Hoz, Shmaryahu

Aurbach, Doron

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Article abstract of DOI:10.1021/jo00192a008

The nucleophilic reaction of PhS^- with 3-chloro- and 3-bromobicyclobutanecarbonitrile (2-Cl(Br)) in MeOH and DME was investigated.The products in MeOH are the dithioketal 3 and the two cis-trans isomers of the thiooxoketal 4.The identity of the

Full text of DOI:10.1021/jo00192a008

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Product name:Bicyclo[1.1.0]butane-1-carbonitrile, 3-(phenylthio)-

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