Synthesis of 1-Acyl-1H-pyrroles from Cyclic 2-(Acylmethyl)-1,3-diketones via Rearrangement involving Transannular Interaction

DOI: 10.1039/c39840000354

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 354 - 355 (1984)

Update date:2022-08-03

Topics:

Authors:

Sammes, Michael P.

Maini, Prem Nath

Katritzky, Alan R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000354

Cyclic 2-(acylmethyl)-1,3-diketones are converted into 1-acyl-1H-pyrroles in high yields by ammonium acetate in acetic acid, via rearrangement of a hydroxypyrroline intermediate.

Full text of DOI:10.1039/c39840000354

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4H-Indol-4-one, 3,3a,5,6,7,7a-hexahydro-7a-hydroxy-3a,6,6-trimethyl-2-phenyl-

Cas No:91165-12-7

R&D Labs maybe for 91165-12-7

Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
LIAOYANG TENGYUAN FOOD ADDITIVE FACTORY

Contact:+86-419-5807666

Address:Haodianzi village,Hanling Town,Liaoyang county
N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Suzhou Time-chem Technologies Co., Ltd.

Contact:0512-63983931/68086856

Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China

Relevant to this article

An efficient and general route to gem-difluoromethylenated α,β-unsaturated δ-lactones: High enantioselective synthesis of gem-difluoromethylenated goniothalamins

Doi:10.1021/jo061012r
(2006)
N-(Methyloxycarbonyl)thiophene sulfonamides as high affinity AT2 receptor ligands

Doi:10.1016/j.bmc.2020.115859
(2021)
Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals

Doi:10.1039/c4cc09850a
(2015)
Improving the affinity of SL0101 for RSK using structure-based design

Doi:10.1021/ml300298v
(2013)
"One-poto" synthesis of 4-substituted 1,5-diaryl-1H-pyrazole-3- carboxylic acids via a MeONa/LiCl-mediated sterically hindered claisen condensation-Knorr reaction-hydrolysis sequence

Doi:10.1055/s-0032-1317668
(2012)
Thietane and Selenetane Complexes by Thermal Cycloaddition of Vinyl Ethers to Transition-Metal-Coordinated Thio- And Selenoaldehydes - Crystal Structure of Pentacarbony(7-phenyl-2-oxa-8-thiabicyclo[4.2.0]octane-S)tungsten(0)

Doi:10.1002/cber.19961291005
(1996)

Article Doi