Synthesis of 1-Acyl-1H-pyrroles from Cyclic 2-(Acylmethyl)-1,3-diketones via Rearrangement involving Transannular Interaction

DOI: 10.1039/c39840000354

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 354 - 355 (1984)

Update date:2022-08-03

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Authors:

Sammes, Michael P.

Maini, Prem Nath

Katritzky, Alan R.

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Article abstract of DOI:10.1039/c39840000354

Cyclic 2-(acylmethyl)-1,3-diketones are converted into 1-acyl-1H-pyrroles in high yields by ammonium acetate in acetic acid, via rearrangement of a hydroxypyrroline intermediate.

Full text of DOI:10.1039/c39840000354

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