
Journal of Organometallic Chemistry p. 17 - 24 (1984)
Update date:2022-08-04
Topics:
Tzschach, A.
Uhlig, W.
Kellner, K.
(Dialkylaminomethyl)chlorosilanes have been obtained by the reaction of trichlorosilane with bis(dimethylamino)methane.The corresponding stannanes have been prepared by the addition of methyleneimmonium halides to SnCl2.In the silicon compounds a covalent <*>Si-CH2-N= bond is observed, while the tin compounds have ionic structures.Reactions of the new compounds are described.
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