Methyleneindolines, Indolenines, and Indoleniniums. 18. A Biomimetic Entry in the Melodinus Alkaloids

DOI: 10.1021/jo00192a005

Source and publish data:

Journal of Organic Chemistry p. 3275 - 3277 (1984)

Update date:2022-08-04

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Authors:

Hugel, Georgette

Levy, Jean

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Article abstract of DOI:10.1021/jo00192a005

The chloroindolenine 4a derived from vincadifformine (1a) was reduced to aziridine 5a.Flow thermolysis of 5a at 400 deg C yielded imine 6a, which was further oxidized to tetrahydroscandine (2a).Tetrahydromeloscine (3a) was prepared from 2a following literature procedures.

Full text of DOI:10.1021/jo00192a005

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