Tetrahedron p. 6857 - 6866 (1998)
Update date:2022-07-29
Topics:
Lang'at, Caroline C.
Watt, Robert A.
Toth, Istvan
Phillipson, J. David
A series of simple bicyclic analogues of quassinoids have been prepared including compounds with ring A typical of bruceolides and dehydrobruceolides. The synthesis of bicyclic compound 5 and tricyclic analogue 6 was accomplished by acid catalysed Robinson Annelation reaction. Hydroxyketone 9a and its 2-substituted analogues were also prepared to study the structure activity relationship.
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