USES OF Si-N BONDS IN ORGANIC SYNTHESIS. A DIRECT SYNTHESIS OF FUNCTIONAL PROTECTED PROPARGYLIC PRIMARY AMINES.

DOI: 10.1016/S0040-4039(01)90067-X

Source and publish data:

Tetrahedron Letters p. 1887 - 1890 (1984)

Update date:2022-08-05

Topics:

Authors:

Corriu, Robert J. P.

Huynh, Vilam

Moreau, Joel J. E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)90067-X

An easy route to lithium N,N-bis(trimethylsilyl)aminomethylacetylide 1 is described.Reactions of 1 with electrophiles give rise to various protected primary amines.

Full text of DOI:10.1016/S0040-4039(01)90067-X

Products guided by the article

Product name:Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-N-[3-[1-[(trimethylsilyl)oxy]-2-cyclohexen -1-yl]-2-propynyl]-

Cas No:91375-39-2

R&D Labs maybe for 91375-39-2

H&Y International Group Ltd

Contact:+86-571-86491666

Address:SHI XIANG ROAD
HAINAN JINYING IMPORT AND EXPORT CO. LTD

Contact:+86-898-32875423

Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.

Contact:+86-(574)-81110986

Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Shanghai Hope Chem Co., Ltd

website:http://www.hope-chem.com

Contact:86-21-58090396-805

Address:Floor 4, Building 5, No.588 Tianxiong Road, Zhoupu International Medical Zone, ShangHai, China

Relevant to this article

Synthesis of 2-tetralone derivatives by Bi(OTf)₃-catalyzed intramolecular hydroarylation/isomerization of propargyl alcohols

Doi:10.1016/j.tetlet.2014.12.129
(2015)
1,3-Oxazine-2-one derived dual-targeted molecules against replicating and non-replicating forms of Mycobacterium tuberculosis

Doi:10.1016/j.ejmech.2020.112835
(2020)
Synthesis, structure, and dynamic behavior of tungsten dihydride silyl complexes Cp*(CO)₂W(H)₂(SiHPhR) (R = Ph, H, Cl)

Doi:10.1021/om060101r
(2006)
Development summary towards a manufacturable process for R 83842 [(S)-6-[(4-chlorophenyl) (1H-1,2,4-triazol-1-yl)methyl]-1-methyl-1H-benzotriazole]

Doi:10.1021/op990081n
(2000)
2-Phenylindoles. Relationship between Structure, Estrogen Receptor Affinity, and Mammary Tumor Inhibiting Activity in the Rat

Doi:10.1021/jm00377a011
(1984)
N′,2-Diphenylquinoline-4-carbohydrazide based NK₃ receptor antagonists II

Doi:10.1016/j.bmcl.2006.08.085
(2006)

Article Doi