Tetrahedron Letters p. 2201 - 2204 (1984)
Update date:2022-08-04
Topics:
Schiess, P.
Eberle, M.
Huys-Francotte, M.
Wirz, J.
Ortho-quinoid vinylketenes 2 have been generated thruogh flash photolysis of benzocyclobutenones 1.A kinetic study of intermolecular addition reactions of 2 competing with the recyclization 2 -> 1 reveals strikingly different substituent effects for the addition of methanol and of dienophiles.
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