Journal of the Chemical Society. Chemical communications p. 1229 - 1231 (1984)
Update date:2022-08-04
Topics:
Malik, Abdul
Kowollik, Wolfgang
Scheer, Peter
Afza, Nighat
Voelter, Wolfgang
A new class of pharmacologically interesting compounds has been synthesized through a novel SN2 displacement of the CF3SO2 group in benzyl 2,3-anhydro-4-trifluoromethylsulphonyl-α-D-ribopyranoside (1) and its β-L-isomer (2), by a variety of suitably protected naturally occurring amino acids: the reaction pathway also provides an efficient route to benzyl 2,3-anhydro-β-L- and -α-D-lyxopyranosides <(3) and (4) respectively>.
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