Synthesis and stability of a homologous series of triynol natural products and their analogues

DOI: 10.1021/jo061588g

Source and publish data:

Journal of Organic Chemistry p. 8982 - 8985 (2006)

Update date:2022-07-30

Topics:

Authors:

Luu, Thanh

Tykwinski, Rik R.

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Article abstract of DOI:10.1021/jo061588g

A series of polyyne natural products 1, 13, and 31 and analogues 14, 21, and 22 are synthesized in six steps. The key step is a Fritsch-Buttenberg- Wiechell rearrangement in which a triyne framework is formed from the appropriate dibromoolefin precursor.

Full text of DOI:10.1021/jo061588g

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