Journal of the American Chemical Society p. 14264 - 14265 (2006)
Update date:2022-08-03
Topics:
Arp, Forrest O.
Fu, Gregory C.
The first method for the kinetic resolution of indolines through catalytic N-acylation is described. To improve the selectivity factor, new planar-chiral PPY-derived catalysts were synthesized, wherein the chiral environment was systematically modified. This work provides a rare example of a nonenzyme-based acylation catalyst for the kinetic resolution of amines. Copyright
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(2006)
