PALLADIUM-CATALYZED CHIRALITY TRANSFER OF 1,3-DIENE MONOEPOXIDES AND ITS APPLICATION TO THE SYNTHESIS OF STEROID SIDE CHAINS

DOI: 10.1016/S0040-4039(01)90076-0

Source and publish data:

Tetrahedron Letters p. 1921 - 1924 (1984)

Update date:2022-07-29

Topics:

Authors:

Takahashi, Takashi

Ootake, Atsushi

Tsuji, Jiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)90076-0

The palladium-catalyzed 1,4-addition of nucleophiles to 15β,16β-epoxy-E-Δ¹⁷⁽²⁰⁾-isoheptylidene steroid 8 and 15β,16β-epoxy-E-Δ¹⁷⁽²⁰⁾-ethylidene steroid 13 has been studied as a good method for regio- and stereoselective introduction of steroid side chains.

Full text of DOI:10.1016/S0040-4039(01)90076-0

Products guided by the article

Product name:2-{(S)-1-[(3S,10R,13S,15R)-3-(tert-Butyl-dimethyl-silanyloxy)-15-hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15-dodecahydro-1H-cyclopenta[a]phenanthren-17-yl]-ethyl}-5-methyl-3-oxo-hexanoic acid methyl ester

Cas No:91708-65-5

R&D Labs maybe for 91708-65-5

Guangzhou Swan Chemical Co., Ltd.

Contact:+86-20-31075659

Address:NO.301, Hong ba fang investment BLDG 1,Guan chong village,Shiqi town,Panyu district,Guangzhou
Josun International Limited

website:http://www.josunpharma.com

Contact:+86-311-80715268 80766839

Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China
GIHI CHEMICALS CO.,LIMITED

Contact:+86-571-86217390

Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai

Relevant to this article

Synthetic, spectroscopic, structural, and electrochemical investigations of ferricenium derivatives with weakly coordinating anions: ion pairing, substituent, and solvent effects

Doi:10.1039/d1dt01192h
(2021)
Doi:10.1021/jo01050a033
(1962)
Total synthesis of platensimycin

Doi:10.1002/anie.200603892
(2006)
Doi:10.1021/ie50361a004
(1940)
STEREOSPECIFIC SYNTHESIS OF LEUKOTRIENE B4 (LTB4)

Doi:10.1016/S0040-4039(00)86935-X
(1982)
A novel indicator series for measuring pK_a values in acetonitrile

Doi:10.1016/j.tet.2004.05.019
(2004)

Article Doi