PALLADIUM-CATALYZED CHIRALITY TRANSFER OF 1,3-DIENE MONOEPOXIDES AND ITS APPLICATION TO THE SYNTHESIS OF STEROID SIDE CHAINS

DOI: 10.1016/S0040-4039(01)90076-0

Source and publish data:

Tetrahedron Letters p. 1921 - 1924 (1984)

Update date:2022-07-29

Topics:

Authors:

Takahashi, Takashi

Ootake, Atsushi

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(01)90076-0

The palladium-catalyzed 1,4-addition of nucleophiles to 15β,16β-epoxy-E-Δ¹⁷⁽²⁰⁾-isoheptylidene steroid 8 and 15β,16β-epoxy-E-Δ¹⁷⁽²⁰⁾-ethylidene steroid 13 has been studied as a good method for regio- and stereoselective introduction of steroid side chains.

Full text of DOI:10.1016/S0040-4039(01)90076-0

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