Organometallics p. 1589 - 1591 (1984)
Update date:2022-08-05
Topics:
Macomber, David W.
W(CO)5[C(OMe)CH2R1] (R1 = H, CH3) reacts with PhC2R2 (R2 = Ph, CH3) in toluene at 100°C to give vinyl ethers and enones. The formation of these products can be explained by an exocyclic β-hydride elimination reaction of a metallacyclobutene intermediate.
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Doi:10.1002/anie.202007403
(2020)Doi:10.1207/S15324796ABM2303_6
(1933)Doi:10.1021/jo00385a011
(1987)Doi:10.1002/ejoc.200600550
(2006)Doi:10.1016/j.tetasy.2006.09.022
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(2006)
