Tetrahedron Letters p. 2303 - 2306 (1984)
Update date:2022-08-05
Topics:
Gilbert, John C.
Senaratne, K. P. A.
Base-promoted reaction of ketones and diethyl (diazomethyl)phosphonate in the presence of allylic amines affords allylic enamines in good yields.These enamines undergo <3,3>-sigmatropic rearrangement upon alkylation and heating at 80 deg C to iminium salts which can be hydrolyzed to aldehydes.The procedure allows generation of quaternary carbon centers under mild reaction conditions.
View MoreChengdu ZY Biochemical Technology Co., LTD
Contact:0086-28-88680086
Address:170 Qingpu Road, Shouan Town, Pujiang County
shanghai tuomiao chemicial co.,ltd.
website:https://www.tuomiaochem.com/
Contact:021 - 59853336
Address:shanghai
Chengdu Sino-Strong Pharmaceutical Co.,Ltd.
website:http://www.sino-strong.com.cn
Contact:+86-28-82666753
Address:459 West haike road,Cross-straits technological industry park, Wenjiang district,Chengdu, P.R.China
Beijing Merson Pharmaceutical Co., Ltd
Contact:0086-10-80484934 0086-10-80484574/
Address:2nd Floor , No. 2 Building , No. 14 Houshayu Duan, Jingmi Road ,Shunyi District , Beijing 101318, P.R.China
Xinchang Yueding Chemical Co., Ltd.
Contact:86-571-56926323
Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Doi:10.1021/ja00336a003
(1984)Doi:10.1002/chem.200600332
(2006)Doi:10.1016/j.tet.2006.11.042
(2007)Doi:10.1021/om0607144
(2007)Doi:10.1021/ol062485n
(2006)Doi:10.1021/acs.joc.6b01199
(2016)
