Stereospecific Introduction of an Asymmetric Centre at C-6 in a Glycoside

DOI: 10.1039/c39840000659

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 659 - 661 (1984)

Update date:2022-07-29

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Authors:

Nicoll-Griffith, Deborah

Weiler, Larry

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Article abstract of DOI:10.1039/c39840000659

Stereospecific addition of Me2Cu(CN)Li2 to a bicyclic conjugated lactone, derived from D-glucose via an intramolecular Wadsworth-Emmons reaction, affords a rational route to introduce a chiral centre at C-6 on the glucose skeleton.

Full text of DOI:10.1039/c39840000659

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