Bulletin of the Chemical Society of Japan p. 1421 - 1422 (1984)
Update date:2022-08-03
Topics: Regioselectivity Column chromatography Yield NMR spectroscopy Kinetic studies Stereoselectivity Catalysis Reaction Monitoring Stereochemical analysis Sulfonylation Electrophilic addition Ruthenium(II) complex Arenesulfonyl chlorides Solvent Optimization
Kamigata, Nobumasa
Narushima, Tomoo
Sawada, Hideo
Kobayashi, Michio
The reactions of arenesulfonyl chlorides with cis- or trans-β-methylstyrene catalyzed by dichlorotris(triphenylphosphine)ruthenium(II) in the presence of triethylamine proceeded smoothly to give only (E)-2-arylsulfonyl-1-phenylpropene.The recovered cis-β-methylstyrene was isomerized to trans form, while trans-β-methylstyrene did not isomerize to the cis one.
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Doi:10.1246/cl.1984.1143
(1984)Doi:10.1002/chem.200600260
(2006)Doi:10.1016/j.tet.2006.10.083
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