European Journal of Organic Chemistry p. 3145 - 3151 (2017)
Update date:2022-08-05
Topics:
Wan, Wen
Xu, Xiaochen
Chen, Yunrong
Jiang, Haizhen
Wang, Yong
Deng, Hongmei
Hao, Jian
An AgI-mediated ethoxycarbonyldifluoromethylation of isocyanides has been developed. This radical cascade reaction involves the addition of difluoromethylene radical to the isocyanide functionality, and subsequent homolytic aromatic substitution to give difluoromethylated phenanthridines with a good functional-group tolerance.
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