Journal of Organometallic Chemistry p. 11 - 18 (1984)
Update date:2022-08-04
Topics:
Borisova, I. V.
Luzikov, Yu. N.
Zemlyansky, N. N.
Ustynyuk, Yu. A.
Beletskaya, I. P.
Reactions of the compounds of the R2R'EC29H21 type (R = Alk; R'Alk,Cl; E = Si, Ge, Sn; C29H21 = 1,2,3,4-tetraphenylcyclopentadiene-5-yl) with Ph3P=CMe2 were carried out.As was shown for Me3GeC29H21 by 13C and 31P NMR spectroscopy, the reactions proceed in the direction of demetallation (kinetic control) and deprotonation (thermodynamic control); the salts
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(1983)
