A GENERAL SYNTHESIS OF OPTICALLY ACTIVE PHOSPHINES, PHOSPHINITES AND THIOPHOSPHINITES FROM ALKYLTHIO(ALKYLSELENO)PHOSPHONIUM SALTS AND TRIS(DIMETHYLAMINO)PHOSPHINE AS A THIOPHILIC AGENT

DOI: 10.1016/S0040-4039(01)81213-2

Source and publish data:

Tetrahedron Letters p. 2493 - 2496 (1984)

Update date:2022-08-04

Topics:

Authors:

Omelanczuk, J.

Mikolajczyk, M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81213-2

Tris(dimethylamino)phosphine was found to be a suitable thiophilic reagent which converts optically active alkylthio(alkylseleno)phosphonium salts into chiral tertiary phosphines and phosphonites with a high stereoselectivity.The first synthesis of optically active thiophosphinites from bis(alkylthio)phosphonium salts and tris(dimethylamino)phosphine is also reported.

Full text of DOI:10.1016/S0040-4039(01)81213-2

Products guided by the article

Product name:C₁₁H₁₇PS

Cas No:92682-85-4

R&D Labs maybe for 92682-85-4

Daicel Chiral Technologies (China)CO.,LTD

Contact:021-5046-0086*8

Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china
Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui

Relevant to this article

Total syntheses of novel dideoxynucleoside analogues using chiral amino acids

Doi:10.1016/S0040-4039(00)01004-2
(2000)
Protic Ionic Liquid Promoted One Pot Synthesis of 2-amino-4-(phenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carbonitrile Derivatives in Water and Their Antimycobacterial Activity

Doi:10.1002/jhet.3133
(2018)
Doi:10.1021/jm00300a021
(1970)
Efficient red phosphorescent oleds using Ir(III) complexes based on bezoylphenylpyridine and the various ancillary ligands

Doi:10.1166/jnn.2014.8441
(2014)
Doi:10.1007/BF00480650
()
Facile syntheses of ABC ring skeleton of camptothecin and related alkaloids

Doi:10.1081/SCC-200028560
(2004)

Article Doi