A GENERAL SYNTHESIS OF OPTICALLY ACTIVE PHOSPHINES, PHOSPHINITES AND THIOPHOSPHINITES FROM ALKYLTHIO(ALKYLSELENO)PHOSPHONIUM SALTS AND TRIS(DIMETHYLAMINO)PHOSPHINE AS A THIOPHILIC AGENT

DOI: 10.1016/S0040-4039(01)81213-2

Source and publish data:

Tetrahedron Letters p. 2493 - 2496 (1984)

Update date:2022-08-04

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Authors:

Omelanczuk, J.

Mikolajczyk, M.

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Article abstract of DOI:10.1016/S0040-4039(01)81213-2

Tris(dimethylamino)phosphine was found to be a suitable thiophilic reagent which converts optically active alkylthio(alkylseleno)phosphonium salts into chiral tertiary phosphines and phosphonites with a high stereoselectivity.The first synthesis of optically active thiophosphinites from bis(alkylthio)phosphonium salts and tris(dimethylamino)phosphine is also reported.

Full text of DOI:10.1016/S0040-4039(01)81213-2

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