Tetrahedron Letters p. 2493 - 2496 (1984)
Update date:2022-08-04
Topics:
Omelanczuk, J.
Mikolajczyk, M.
Tris(dimethylamino)phosphine was found to be a suitable thiophilic reagent which converts optically active alkylthio(alkylseleno)phosphonium salts into chiral tertiary phosphines and phosphonites with a high stereoselectivity.The first synthesis of optically active thiophosphinites from bis(alkylthio)phosphonium salts and tris(dimethylamino)phosphine is also reported.
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