A GENERAL SYNTHESIS OF OPTICALLY ACTIVE PHOSPHINES, PHOSPHINITES AND THIOPHOSPHINITES FROM ALKYLTHIO(ALKYLSELENO)PHOSPHONIUM SALTS AND TRIS(DIMETHYLAMINO)PHOSPHINE AS A THIOPHILIC AGENT

DOI: 10.1016/S0040-4039(01)81213-2

Source and publish data:

Tetrahedron Letters p. 2493 - 2496 (1984)

Update date:2022-08-04

Topics:

Authors:

Omelanczuk, J.

Mikolajczyk, M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81213-2

Tris(dimethylamino)phosphine was found to be a suitable thiophilic reagent which converts optically active alkylthio(alkylseleno)phosphonium salts into chiral tertiary phosphines and phosphonites with a high stereoselectivity.The first synthesis of optically active thiophosphinites from bis(alkylthio)phosphonium salts and tris(dimethylamino)phosphine is also reported.

Full text of DOI:10.1016/S0040-4039(01)81213-2

Products guided by the article

Product name:C₁₁H₁₇PS

Cas No:92682-85-4

R&D Labs maybe for 92682-85-4

Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Changzhou Xuanming Chemical Co., Ltd.

Contact:86 0519 85525329

Address:China Town, Xinbei, Changzhou, Jiangsu Room 6019
Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang

Relevant to this article

Total syntheses of novel dideoxynucleoside analogues using chiral amino acids

Doi:10.1016/S0040-4039(00)01004-2
(2000)
Protic Ionic Liquid Promoted One Pot Synthesis of 2-amino-4-(phenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carbonitrile Derivatives in Water and Their Antimycobacterial Activity

Doi:10.1002/jhet.3133
(2018)
Doi:10.1021/jm00300a021
(1970)
Efficient red phosphorescent oleds using Ir(III) complexes based on bezoylphenylpyridine and the various ancillary ligands

Doi:10.1166/jnn.2014.8441
(2014)
Doi:10.1007/BF00480650
()
Facile syntheses of ABC ring skeleton of camptothecin and related alkaloids

Doi:10.1081/SCC-200028560
(2004)

Article Doi