Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3431 - 3438 (1986)
Update date:2022-08-05
Topics:
Sorek, Yacov
Cohen, Haim
Meyerstein, Dan
The free radicals .CH2CH2OH and .CH(CH3)CH2OH react with iron(II)protoporphyrin, FeIIPP, to form the transient complexes (PP)FeII-CHRCH2OH> The spectra of these complexes are reported.The transient complexes decompose in a first-order process via the reaction (PP)FeII-CHRCH2OH -> FeIIIPP + OH(1-) + CH2=CHR.The specific rates of the latter reactions are 80 and 40 s-1 for the two systems, respectively.The results are compared with those for analogous process.
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