Unusual Macrocyclic Biphenyls Containing the Dihydropyrene Nucleus. An Observation of Aryl Group Transfer from Phosphine to Aryl Halide Using Nickel Complexes

DOI: 10.1021/ja00337a021

Source and publish data:

Journal of the American Chemical Society p. 7776 - 7779 (1984)

Update date:2022-07-29

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Authors:

Mitchell, Reginald H.

Chaudhary, Mahima

Dingle, Thomas W.

Williams, Richard Vaughan

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Article abstract of DOI:10.1021/ja00337a021

Coupling of 2-bromo-trans-10b,10c-dimethyl-10b,10c-dihydropyrene (5) by using bis(triphenylphosphino)nickel(II) chloride yielded not only the expected biaryl 2 but also the phenyldihydropyrene 3.The latter must have arisen through an aryl transfer from th

Full text of DOI:10.1021/ja00337a021

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