CYANATION OF ACETALS WITH t-BUTYL ISOCYANIDE-TiCl4 SYSTEM

DOI: 10.1246/cl.1984.937

Source and publish data:

Chemistry Letters p. 937 - 940 (1984)

Update date:2022-08-05

Topics: Yield NMR spectroscopy Catalyst Reaction Conditions Cyanation Acetals TiCl4

Authors:

Ito, Yoshihiko

Imai, Hiroshi

Segoe, Kazuo

Saegusa, Takeo

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Article abstract of DOI:10.1246/cl.1984.937

Cyanation of acetals was achieved by t-butyl isocyanide in the presence of TiCl4, producig cyanohydrin ethers in good yields. β-(Trimethylsilyl)ethyl isocyanide in the combination with TiCl4 effected the cyanation as well.

Full text of DOI:10.1246/cl.1984.937

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