Chemical and Pharmaceutical Bulletin p. 410 - 412 (1994)
Update date:2022-08-04
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Yamano
Ito
The first total synthesis of optically active fucoxanthin 1 has been accomplished via the 8-oxo-compound 7, efficiently prepared by rearrangement of the α-acetylenic alcohol 2 using oxo-metallic catalyst and subsequent iodine catalyzed double bond-shift.
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