Regioselectivity in Organo-transition-metal Chemistry. A Remarkable Steric Effect in ?-Allyl Palladium Chemistry

DOI: 10.1039/c39840000648

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 648 - 650 (1984)

Update date:2022-08-04

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Authors:

Keinan, Ehud

Sahai, Mahendra

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Article abstract of DOI:10.1039/c39840000648

The regioselectivity of the palladium catalysed allylic substitution by several representative nucleophiles was found to be highly dependent on very small steric differences that exist at the two ends of the allylic system: attack by stabilized nucleophil

Full text of DOI:10.1039/c39840000648

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