Regioselectivity in Organo-transition-metal Chemistry. A Remarkable Steric Effect in ?-Allyl Palladium Chemistry

DOI: 10.1039/c39840000648

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 648 - 650 (1984)

Update date:2022-08-04

Topics:

Authors:

Keinan, Ehud

Sahai, Mahendra

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000648

The regioselectivity of the palladium catalysed allylic substitution by several representative nucleophiles was found to be highly dependent on very small steric differences that exist at the two ends of the allylic system: attack by stabilized nucleophil

Full text of DOI:10.1039/c39840000648

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzene, [(1-methyl-2-hexenyl)oxy]-

Cas No:92776-34-6

R&D Labs maybe for 92776-34-6

Evershine Chemical CO Ltd

Contact:+86-571-87010026

Address:202, Zhenhua Road,
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Sino-Japan Chemical Co., Ltd.

website:http://www.sjc.com.tw

Contact:(886) 2-2396-6223

Address:14Fl., No. 99. Sec. 2, Jen Ai Road
Sino-Japan Chemical Co., Ltd.

website:http://www.sjc.com.tw

Contact:(886) 2-2396-6223

Address:14Fl., No. 99. Sec. 2, Jen Ai Road
Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.

Relevant to this article

Slow-onset, long-duration, alkyl analogues of methylphenidate with enhanced selectivity for the dopamine transporter

Doi:10.1021/jm0608614
(2007)
DER 2-(4-PYRIDYL)ETHOXYCARBONYL-(4-Pyoc)-REST - EINE HYDROPHILE, SAEURE- UND BASENSTABILE AMINOSCHUTZGRUPPE FUER DIE PEPTIDSYNTHESE

Doi:10.1016/S0040-4039(01)91077-9
(1984)
Installation of an aryl boronic acid function into the external section of N-aryl-oxazolidinones: Synthesis and antimicrobial evaluation

Doi:10.1016/j.ejmech.2020.113002
(2021)
Phenylglycine as a novel P2 scaffold in hepatitis C virus NS3 protease inhibitors

Doi:10.1016/j.bmc.2006.11.003
(2007)
Five-coordinate Pd(ii) orthometallated triarylphosphite complexes

Doi:10.1039/b613524b
(2007)
Metal-free entry to phosphonylated isoindoles by a cascade of 5-exo-dig cyclization, a [1,3]-alkyl shift, and aromatization under microwave heating

Doi:10.1021/ol062817o
(2007)

Article Doi