Absolute Configuration of Multifidene as Deduced by Total Synthesis of the Unnatural Levorotatory Enantiomer

DOI: 10.1021/jo00197a038

Source and publish data:

Journal of Organic Chemistry p. 4516 - 4518 (1984)

Update date:2022-09-26

Topics:

Authors:

Paquette, Leo A.

Coghlan, Michael J.

Hayes, Peter C.

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Article abstract of DOI:10.1021/jo00197a038

The powerful sperm attractant of the brown alga Cutleria multifida (+)-multifidene (1), is shown to possess the 3S,4S configuration.The protocol, which parallels our earlier synthesis of the racemic polyolefinic hydrocarbon, begins with (-)-cis-(5-vinyl-2

Full text of DOI:10.1021/jo00197a038

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