N.M.R. Evidence for a Fluxional Allyl-hydride Species featuring an Aliphatic C-H...IrIII Interaction

DOI: 10.1039/c39810000506

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 506 - 507 (1981)

Update date:2022-07-30

Topics:

Authors:

Howarth, Oliver W.

McAteer, Colin H.

Moore, Peter

Morris, George E.

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Article abstract of DOI:10.1039/c39810000506

The 3-2,3-dimethylbutenyl)>+ ion has been identified in CD2Cl2 solution from its 1H, 2H, and 31P n.m.r. spectra, which reveal a novel C-H...Ir^III interaction and a fluxional process involving facile hydrogen transfer between metal and hydrocarbon.

Full text of DOI:10.1039/c39810000506

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