Tetrahedron p. 2931 - 2935 (1986)
Update date:2022-07-29
Topics:
Reetz, M. T.
Kyung, S. H.
Huellmann, M.
Treatment of CH3Li or CH3MgCl with TiCl4 results in quantitative formation of CH3TiCl3, a non-basic reagent which reacts chemo- and stereoselectively with carbonyl compounds.It is considerably more reactive than the alkoxy analogue CH3Ti(OCHMe2)3.This means that selective addition to ketones
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