PREPARATION AND PROPERTIES OF GROUP 8 TRANSITION METAL ALKOXIDES RELEVANT TO CATALYTIC HYDROGENATION OF KETONES TO ALCOHOLS

DOI: 10.1246/cl.1984.1363

Source and publish data:

Chemistry Letters p. 1363 - 1366 (1984)

Update date:2022-07-30

Topics:

Authors:

Hayashi, Yoshinori

Komiya, Sanshiro

Yamamoto, Takakazu

Yamamoto, Akio

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Article abstract of DOI:10.1246/cl.1984.1363

Alkoxo complexes, M(OR)L_n and MH(OR)L_n (M=Co, Rh, Ru, L=PPh3; R=CH(CF3)2, CHPh(CF3)), have been prepared by insertion of fluoroketones into M-H bonds in CoH(N2)L3, RhHL4, and RuH2L4.Hydrogenolysis of the Ru- and Rh-alkoxo complexes w

Full text of DOI:10.1246/cl.1984.1363

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