Chemistry Letters p. 1363 - 1366 (1984)
Update date:2022-07-30
Topics:
Hayashi, Yoshinori
Komiya, Sanshiro
Yamamoto, Takakazu
Yamamoto, Akio
Alkoxo complexes, M(OR)Ln and MH(OR)Ln (M=Co, Rh, Ru, L=PPh3; R=CH(CF3)2, CHPh(CF3)), have been prepared by insertion of fluoroketones into M-H bonds in CoH(N2)L3, RhHL4, and RuH2L4.Hydrogenolysis of the Ru- and Rh-alkoxo complexes w
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