REACTION OF PHOTOGENERATED VINYL CATIONS WITH AMBIDENT ANIONS

DOI: 10.1246/cl.1984.1523

Source and publish data:

Chemistry Letters p. 1523 - 1526 (1984)

Update date:2022-08-04

Topics:

Authors:

Kitamura, Tsugio

Kobayashi, Shinjiro

Taniguchi, Hiroshi

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Article abstract of DOI:10.1246/cl.1984.1523

Photolysis of vinyl bromides with cyanate anion in a two-phase system gave only isoquinolinones as the N-site attacked products.However, the photolysis with thiocyanate anion gave the N-site attacked products, isothioquinolinones or vinyl isothiocyanates, and the S.site attacked products, vinyl thiocyanates.

Full text of DOI:10.1246/cl.1984.1523

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