Journal of the Chemical Society. Perkin transactions II p. 1227 - 1232 (1984)
Update date:2022-08-05
Topics:
Yano, Yumihiko
Ohya, Eiichi
Several bisflavins linked at the 10,10'-positions of isoalloxazine rings have been synthesized.The kinetics of the oxidation of N-benzyl-1,4-dihydronicotinamide in aqueous solution have been examined.It has been found that each flavin of a bisflavin is considerably influenced by another intramolecular flavin moiety due to the formation of a charge-transfer complex between intramolecularly reduced and oxidized flavins.The formation of the complex depends on the conformation.
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