Tetrahedron Letters p. 2483 - 2486 (1984)
Update date:2022-08-04
Topics:
Okuda, Yasuhiro
Morizawa, Yoshitomi
Oshima, Koichiro
Nozaki, Hitosi
Whereas CuI catalyzed silylmagnesation of the tosylate of 5-hexyn-1-ol with the title reagent affords dimethylphenylsilylmethylenecyclopentane exclusively, the mesylate of 3-butyn-1-ol gives a mixture of unexpected silylcyclobutene and cyclopropylidene derivative.
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Doi:10.1007/BF00769802
(1984)Doi:10.1039/b617170b
(2007)Doi:10.1016/j.bmcl.2010.09.093
(2010)Doi:10.1002/kin.550270107
(1995)Doi:10.1021/ol502148a
(2014)Doi:10.1016/j.tetlet.2007.11.129
(2008)
