Journal of Organic Chemistry p. 4898 - 4913 (1987)
Update date:2022-08-03
Topics: Regioselectivity Total synthesis Stereoselectivity Prostaglandins
Marino, Joseph P.
Pradilla, Roberto F. de la
Laborde, Edgardo
A systematic study of the reaction between cyclopentene epoxides and alkyl-, alkenyl-, and arylcyanocuprates is described.Alkylcyanocuprates react with complete regio- and stereoselectivity to provide trans-4-alkylcyclopent-2-enols in excellent yields.Vin
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(1964)
