Electrochemical Reduction of Organic Compounds. 22. Preparation of Aromatic Aldehydes by Electroreduction of Esters and Amides in the Presence of Chlorotrimethylsilane

DOI: 10.1002/prac.19933350304

Source and publish data:

Journal fur Praktische Chemie - Chemiker-Zeitung p. 230 - 234 (1993)

Update date:2022-08-05

Topics:

Authors:

Goetz-Schatowitz, P.-R.

Struth, G.

Voss, J.

Wiegand, G.

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Article abstract of DOI:10.1002/prac.19933350304

The electroreduction of aromatic esters 1 and amides 9 in dry acetonitrile in the presence of chlorotrimethylsilane 2 affords aldehydes 3 in moderate to good yields depending on the aromatic substituents.The formation of 3 and characteristic by-products is discussed.

Full text of DOI:10.1002/prac.19933350304

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